Continuous stirred-tank reactor

src: www.pdcmachines.com

The continuous stirred-tank reactor (CSTR), also known as vat- or backmix reactor, is a common model for a chemical reactor in chemical engineering. A CSTR often refers to a model used to estimate the key unit operation variables when using a continuous agitated-tank reactor to reach a specified output. The mathematical model works for all fluids: liquids, gases, and slurries.

The behavior of a CSTR is often approximated or modeled by that of a Continuous Ideally Stirred-Tank Reactor (CISTR). All calculations performed with CISTRs assume perfect mixing. In a perfectly mixed reactor, the output composition is identical to composition of the material inside the reactor, which is a function of residence time and rate of reaction. If the residence time is 5-10 times the mixing time, this approximation is valid for engineering purposes. The CISTR model is often used to simplify engineering calculations and can be used to describe research reactors. In practice it can only be approached, in particular in industrial size reactors.

Video Continuous stirred-tank reactor

The model

Assume:

• perfect or ideal mixing, as stated above

Integral mass balance on number of moles N_i of species i in a reactor of volume V.

${\displaystyle [{\text{accumulation}}]=[{\text{in}}]-[{\text{out}}]+[{\text{generation}}]}$

1. ${\displaystyle {\frac {dN_{i}}{dt}}=F_{io}-F_{i}+V\nu _{i}r_{i}}$

where F_io is the molar flow rate inlet of species i, F_i the molar flow rate outlet, and ${\displaystyle \nu _{i}}$ stoichiometric coefficient. The reaction rate, r, is generally dependent on the reactant concentration and the rate constant (k). The rate constant can be determined by using a known empirical reaction rates that is adjusted for temperature using the Arrhenius temperature dependence. Generally, as the temperature increases so does the rate at which the reaction occurs. Residence time, ${\displaystyle \tau }$, is the average amount of time a discrete quantity of reagent spends inside the tank.

Assume:

• constant density (valid for most liquids; valid for gases only if there is no net change in the number of moles or drastic temperature change)
• isothermal conditions, or constant temperature (k is constant)
• steady state (G_A = r_Av)
• single, irreversible reaction (?_A = -1)
• first-order reaction (r = kC_A)

A -> products

N_A = C_A V (where C_A is the concentration of species A, V is the volume of the reactor, N_A is the number of moles of species A)

2. ${\displaystyle C_{A}={\frac {C_{Ao}}{1+k\tau }}}$

The values of the variables, outlet concentration and residence time, in Equation 2 are major design criteria.

To model systems that do not obey the assumptions of constant temperature and a single reaction, additional dependent variables must be considered. If the system is considered to be in unsteady-state, a differential equation or a system of coupled differential equations must be solved.

CSTR's are known to be one of the systems which exhibit complex behavior such as steady-state multiplicity, limit cycles and chaos.

Maps Continuous stirred-tank reactor

Application

Continuous flow stirred-tank reactors are usually applied in waste water treatment processes. CSTRs facilitate rapid dilution rates which make them resistant to both high pH and low pH volatile fatty acid wastes. CSTRs are less efficient compared to other types of reactors as they require larger reactor volumes to achieve the same reaction rate as other reactor models such as Plug Flow Reactors.

src: i.ytimg.com

See also

src: i.ytimg.com

Notes

src: i.ytimg.com

References

Source of the article : Wikipedia